The rate looks like a percentage but is not written as one, which is where the mistakes come from. $7.50 per $100 does work out to 7.5% of payroll, but the arithmetic runs the other way round: divide payroll by 100 first, then multiply by the rate. Reading the figure as a straight percentage of payroll, or as a flat charge, lands answers a factor of a hundred off in either direction.
Rates vary enormously by classification and by state. Clerical work can rate under a dollar; high-hazard trades can run into the tens of dollars per $100 of payroll.
The rate is why classification matters so much. Moving payroll between two class codes changes premium by the difference between their rates, multiplied across every dollar.